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HS Code |
727560 |
| Product Name | Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium |
| Chemical Formula | C29H17F4IrN4O2 |
| Cas Number | 1038876-32-8 |
| Molecular Weight | 766.67 g/mol |
| Appearance | Yellow to orange crystalline powder |
| Solubility | Soluble in dichloromethane, chloroform, and acetone |
| Melting Point | Decomposes above 300°C |
| Purity | Typically >98% (HPLC) |
| Usage | OLED emitter material |
| Iridium Content | Approximately 25.5% by weight |
As an accredited Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | The product is packaged in a 50 mg amber glass vial, sealed under inert gas, and clearly labeled with product and hazard information. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL): Chemical securely packed in standard drums/cartons, optimized for stability, safe transport, and efficient container space utilization. |
| Shipping | **Shipping Description:** Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium is shipped in a sealed, inert atmosphere container to prevent degradation. Handle with gloves and eye protection. Store at room temperature, away from moisture and light. Non-hazardous for air and ground transport under standard chemical shipment regulations. |
| Storage | Store **Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium** in a tightly sealed container under an inert atmosphere, such as nitrogen or argon. Keep the chemical in a cool, dry, well-ventilated area away from heat, light, and moisture. Avoid contact with strong acids, bases, and oxidizing agents. Handle with appropriate personal protective equipment. |
| Shelf Life | Shelf life: Store Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium in a cool, dry place; stable for 2 years. |
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Purity 99.9%: Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium with purity 99.9% is used in OLED emitter layers, where it ensures high luminescence efficiency. Photoluminescence Quantum Yield >80%: Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium with a photoluminescence quantum yield greater than 80% is used in display backlighting, where it provides enhanced brightness and color purity. Thermal Stability up to 250°C: Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium with thermal stability up to 250°C is used in thermally-processed optoelectronic devices, where it maintains stable emission properties during fabrication. Melting Point 320°C: Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium with a melting point of 320°C is used in high-temperature vacuum deposition, where it enables precise thin film formation. Particle Size <5 μm: Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium with particle size below 5 μm is used in inkjet printing of organic electronics, where it promotes uniform film morphology and device consistency. Electroluminescence Peak 520 nm: Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium with an electroluminescence peak at 520 nm is used in green organic light-emitting diodes, where it delivers saturated emission for vivid color displays. Solubility in Chlorinated Solvents: Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium with solubility in chlorinated solvents is used in solution-processed OLED manufacturing, where it allows for efficient ink formulation and device fabrication. Stability in Ambient Conditions: Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium with high stability in ambient conditions is used in sensor devices, where it improves operational durability and shelf life. |
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Our background in synthesizing advanced iridium complexes stretches back through years of steady investment in ligand innovation, process control, and purity assurance. With Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium at the center, our process teams consistently transform carefully chosen raw materials into a fine-tuned phosphorescent dopant ready for the world’s evolving display needs.
Raw material consistency matters. For this complex, only high-purity difluoro-phenyl and pyridine derivatives make it through our gates. We never skimp on solvent quality, oxygen control, or batch tracking, because small deviations cascade into end-use issues no electronics maker wants. Over time, this painstaking approach has trimmed losses, cut defect rates, and strengthened the photophysical properties that enable high-color OLED lighting and display panels.
Decades in the lab have left our chemists with a measured respect for ligand design. The particular substitution pattern — those two fluorines at the 3 and 5 positions, the snug match of pyridine nitrogen donors — isn’t just academic choice. It shapes the energy transfer, tuning quantum yield and emission wavelengths site by site. Our ligand layout builds on direct customer feedback from panel makers sitting between demanding end users and relentless competition. Every batch captures this learning in solid form.
In hands-on use, customers switch to this molecule when display or lighting designers demand narrow line-width emission, stopped from drifting by the rigid, electron-withdrawing fluorine groups. Long-lifetime, deep-blue or green OLED pixels begin here. Through steady runs, our technicians hit a balance of photostability and emission color, aiming for every shipment to show the same spectral data, not just similar results.
We produce this bis-cyclometalated iridium(III) complex as a fine, powdery solid — free flowing, pale yellow, and never clumped, with off-spec batches immediately flagged. Trace solvent, water, and acid are measured every shift, and our specs for inorganic residue mean less filter clogging and less risk of foreign ion contamination down the user’s production line. Full spectroscopic fingerprints go out with each lot, so there’s no guessing or handwaving about structural fidelity or optical profile.
With this clean material, panel makers press on toward higher external quantum efficiency. After years spent tailoring synthesis, we keep residual metal and organic byproducts beneath our strict in-house control, often surpassing what routine commercial contracts specify. This effort heads off conductivity problems and pixel burn-in — problems industry veterans know can wipe out months of device reliability in just days.
Not all iridium complexes meet the bar set by current high-end OLED producers. On paper, many structures look similar. The truth comes out in device testing, especially under high drive currents or prolonged exposure to ambient moisture. Fluorination at precise sites on the aromatic rings, as embodied in 3,5-difluoro substitution, raises the energy of the triplet excited state, making the molecule more suitable for shorter-wavelength emission. We’ve confirmed, both in our own test runs and in customer lines, that this tweak delivers higher efficiency and improved color purity compared to older, non-fluorinated analogs. Fluorination also tempers molecular aggregation, staving off unwanted shifts in emission over time.
Some compare this molecule to classic fac-tris(2-phenylpyridine)iridium. Our product offers deeper blue photoluminescence and steadier emission spectra across temperature shifts. The introduction of the 2-pyridinecarboxylato ligand in place of a third cyclometalating group subtly tweaks solubility and charge transport. This matters for device architectures where thin film deposition or blending with host matrices calls for tuneable processing windows instead of a one-size-fits-all approach. It means each panel run emerges with fewer dead pixels and better lifetime.
We avoid over-engineering the product into laboratory showpieces with little manufacturability. Everything stems from what works: predictable solubility in typical host materials, melting point consistency, and crystal structure regularity. These choices shorten ramp-up at the user’s fab and let our team swap feedback with process engineers, not just procurement staff, during tech transfer.
This iridium complex follows a disciplined batch model, each drum traceable back to its run and every step logged from ligation through to purification and drying. Our reactors are dedicated for metal-organic intermediates, and we go further than most by implementing zone-controlled inert atmospheres along the full assembly line, not just at the metalation stage. Each run gets a unique lot code with full supporting data — elemental analysis, NMR, mass spectrometry, and luminance testing — before shipment approval. This loop tightens lot-to-lot variation, leaving little to chance on downstream OLED aging tests.
For customers, this translates into minimum requalification work. Many who source from us drop incoming QC from full-screen tests to light-touch confirmation, freeing up staff for higher-value tasks. No maskups, no offcuts, no scrapping hundreds of modules to chase bad chemistry. We take feedback on performance, whether it’s a panel color target or a shift in driving voltage, and actually trace it back to synthesis choices. That two-way street keeps our QC loop grounded in practical device needs, not theoretical metrics alone.
During model upgrades, we gather process engineers, device designers, and suppliers at one table. Nobody skips out on sharing data on film thickness, patterning defects, or stabilities under pulse drive. The result — each version of this complex gets pushed just enough in response to real problems, like solvent compatibility or matrix phase separation. That is how incremental tweaks lead to a robust, production-grade material, not a chemistry curio.
Raw photoluminescence numbers look good in a specification table, but the true test lands in multilayer OLED architectures. It can take months to diagnose whether a material will actually play nice through evaporation or solution processing. Our customer field support group walks through full deposition protocols to spot issues before panels scale up to pilot lines. Static build-up, trace cross-contamination, and side reactions with hosts don’t show up in the literature, but these are regular topics at our collaborative tech calls.
With panel heights getting thinner and emission colors shifting for ultra-high performance displays, every minor improvement in molecular design earns its place. This bis[3,5-difluoro-2-(2-pyridinyl)] iridium system delivers both deeper blue emission peaks and reduced roll-off at practical current densities. We see customer lines start with trial batches for new device builds, dialing in film thickness and host-dopant ratios, long before stepping up to full-scale production. Rapid, reliable communication means fewer surprises, smoother scale-up, and less downtime caused by inconsistent materials.
From time to time, customers ask how our product fares versus lower-cost, “standard” iridium complexes on the open market. Most issues boil down to longevity and color migration. Low-grade analogs often promise similar spectra, yet their purity wavers, they deposit unevenly, and last fewer hours under hard drive. Our in-house analytics spot minor impurities that siphon away long-term device performance, and our recordkeeping lets us quickly diagnose root causes and close the feedback loop.
Device makers who stick with this class of compound experience lower cost of ownership, not just due to quantum efficiency but through smaller maintenance windows, less scrap, and longer panel lifetime for end users. That’s not marketing — that’s the wisdom that comes from years of real-run OLED production diagnostics.
Traders and off-shore distributors may offer similar names, but they rarely share full traceability. We maintain our entire supply chain, audit suppliers for reliability, and retain full chain-of-custody for every reactant and product stream. This means we can supply records for every delivery all the way back to initial raw material purchase, and we invite serious buyers to walk our line for themselves.
Unlike bulk resellers who pass material through uninspected, our QA staff actively intervene, pulling random samples for in-depth LC-MS, ICP-MS, and thermal stress testing. Boxes don’t move forward unless they hit our in-house standard, and we quarantine anything that doesn’t match historical spectral data. We routinely recalibrate our gear, update analytical standards, and cross-validate methods against international reference labs.
On-site chemists don’t just box product; they talk directly with end users, gather feedback, and mash up new batch protocols if real-world results call for iteration. Sometimes, we shift reactor conditions, push temperature profiles, or tweak flushing cycles based on partner insights. Every improvement stacks up in ongoing upgrades, dropping downtime and helping other users down the line.
We protect IP and data integrity by running redundant electronic logs. No records go missing, and only qualified personnel see sensitive details. For downstream producers facing ever-tightening regulatory scrutiny, these measures mean clean audits, rapid documentation, and minimal compliance headaches. More than one partner has dodged shipment delays with our help navigating import or materials conformance questions.
Industry benchmarks for iridium complexes tend to overlook long-haul application data. We set up internal device testing arrays that mimic customer panel lifecycles, with frequent voltage cycling, flash testing, and exposure to thermal stress. Direct feedback from these hands-on trials pushes continued molecular improvements, both in ligand architecture and purification steps.
In OLEDs, panel efficiency often ties back to dopant quantum yield and excited state lifetime. By controlling the 3,5-difluoro pattern and maintaining N-heterocyclic ligand purity, we keep unwanted metal-ligand side species out of the stack. Our internal data tracking shows improved mean time to failure in both rigid and flexible substrate tests compared to comparable, less-refined products.
Our facilities run emission profile comparisons with those from peer-reviewed literature and major competitors, always aiming to match or exceed key figures out of academic white papers without sacrificing scale or financial viability. The outcome — customers adopt new device layers faster, cut pilot testing time, and hit end-user spec targets earlier in the design cycle.
Feedback runs in both directions. Several display makers bring new stack architectures to us, seeking a partner who will co-optimize both compound and process. Our ability to modulate ligand designs — within a strictly controlled framework — lets us chase the balance between color tuning, film thickness, and host/dopant ratio with actual end-product performance in mind.
As countries strengthen regulations around rare metals, precursors, and byproduct management, we invest ahead in compliance. Material safety and environmental standards keep evolving. Rather than scramble at the last minute, we track regulatory moves in real time and preemptively adjust batch recordkeeping, reporting practices, and even raw material sourcing as rules shift.
We do more than tick off compliance boxes on heavy metal limits or solvent residuals. We work with buyers to pre-clear our products for use in diverse jurisdictions, providing certificate records and ongoing regulatory updates. This lets device makers launch into global markets without running afoul of surprise bans or import blocks.
Onsite environmental management includes closed-loop solvent recycling, active waste tracking, and annual review of emissions — driven by real reporting, not just paperwork. For us, these aren’t empty signs hung to impress auditors. Each measure came out of specific incidents: a venting valve tweak that cut halogen emissions, a solvent filter improvement that lowered VOC reports, a stepwise batch-waste separation that let us reclaim more iridium and minimize landfill output.
Much as the spotlight tends to shine on color, photoluminescent output, and device efficiency, the real world demands a broader focus: worker safety, global trade compliance, and long-term environmental stewardship. We openly share incident reports and solutions with our customers — part of earning trust in a sector that tolerates little secrecy or shortcutting.
The best measure of a specialty chemical’s value isn’t how it looks inside a catalog or on a certificate of analysis, but how well it performs after thousands of hours inside active panels. This iridium complex draws from field experience across dozens of panel shops, lighting manufacturers, and research consortia. Each batch stems from feedback, diagnostics, and constant cycle refinement.
Panel makers pushing the frontier on color tuning and device reliability find fewer defects, less yield loss, and steadier color with each new lot. Our thorough partnering — from synthesis, through to testing, delivery, and after-sale support — closes the usual gap between fine-chemical manufacturing and practical industry impact.
As the push for more vibrant, longer-lasting OLEDs continues, compounds like Bis[3,5-difluoro-2-(2-pyridinyl-kN)phenyl-kC](2-pyridinecarboxylato-kN1,kO2)-Iridium signal what a close manufacturer-customer alliance can achieve: tangible, field-tested progress in an ever more demanding industry.