Naphthol AS-KB

    • Product Name: Naphthol AS-KB
    • Chemical Name (IUPAC): 3-(4-chloro-2-methylphenylamino)-4-methyl-1-naphthol
    • CAS No.: 135-65-9
    • Chemical Formula: C17H12ClNO3
    • Form/Physical State: Powder
    • Factroy Site: No.968 Jiangshan Rd., Nantong ETDZ, Jiangsu, China
    • Price Inquiry: sales7@boxa-chem.com
    • Manufacturer: Nantong Acetic Acid Chemical Co., Ltd.
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    Specifications

    HS Code

    650454

    Chemical Name Naphthol AS-KB
    Cas Number 135-65-9
    Molecular Formula C16H11NO3
    Molecular Weight 265.27
    Appearance Light yellow powder
    Melting Point 184-186°C
    Solubility Slightly soluble in ethanol, insoluble in water
    Usage Coupling component in azo dye manufacture
    Synonyms 3-Keto-benzanilide, N-(4-chloro-2-benzoylphenyl)-2-hydroxy-naphthalene-3-carboxamide
    Storage Conditions Store in a cool, dry place, keep container tightly closed

    As an accredited Naphthol AS-KB factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging for Naphthol AS-KB contains 25 kg of product, sealed in a high-density polyethylene drum with a secure lid.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for Naphthol AS-KB: Typically packed 10-20mt per 20′ FCL, in 25kg bags, palletized or non-palletized.
    Shipping **Naphthol AS-KB** should be shipped in tightly sealed containers, protected from moisture and direct sunlight. Handle with care, avoiding physical damage. Transport in compliance with local, national, and international chemical safety regulations. It is classified as a non-hazardous material, but avoid incompatible substances and store separately from foodstuffs and strong oxidizers.
    Storage Naphthol AS-KB should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from sources of ignition and incompatible substances such as strong oxidizing agents. Protect it from moisture and direct sunlight. Ensure proper labeling and keep the storage area equipped with appropriate spill control and fire-fighting equipment.
    Shelf Life Naphthol AS-KB has a typical shelf life of 2 years when stored in a cool, dry, and tightly sealed container.
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    Certification & Compliance
    More Introduction

    Naphthol AS-KB: Putting Chemical Expertise Into Every Batch

    Crafting Naphthol AS-KB to Consistent Quality

    In the world of color chemistry, reliability comes from practice and attention to the details that can get overlooked in larger-scale operations. We’ve spent decades running large reactors, splitting feeds, and monitoring temperature profiles hour after hour in order to produce Naphthol AS-KB that dyers, printers, and coatings formulators trust. This compound, a derivative from the anthranilic acid route, carries the CAS number 135-65-9 and features as one of those cornerstone intermediates in pigment and dye synthesis.

    Producing Naphthol AS-KB is not a one-step affair. The quality always depends on the purity of raw materials like 4-chloro-2-nitroaniline, the pressure balance in hydrogenation, and how thoroughly each batch gets washed and filtered after the coupling stage. We do not treat it merely as a commodity bulk product. Instead, our plant technicians make frequent spot-checks during every shift, sampling for content of free acids and residual ash, since these traces affect everything from shade to fastness in final pigments.

    What Sets Our Naphthol AS-KB Apart

    Anyone who has spent time in a pigment mill or a dye-bath knows not every naphthol powder reacts the same way. Naphthol AS-KB is not another generic intermediate; it’s the backbone for multiple azo pigment formulations used across textiles, plastics, and coatings. The characteristics that matter most are solubility, reactivity with diazo salts, speed of dispersion in water or solvent mixes, and a color tone that stays true after exposure to light and heat.

    Our batches display tight control over melting point (usually in the 180-184°C range), appearance (just off-white to pale beige fine powder), and have low iron and heavy metal content. This matters in high-value applications like calendared textiles, where impurities can lead to dullness or uneven finish after curing and washing cycles. We calibrate the pH within the right window to help partners achieve reproducible coupling reactions on both cotton and synthetics.

    Why Naphthol AS-KB Remains a Mainstay for Color Makers

    Azo pigments and dyes remain among the most widely used colorants worldwide. Naphthol AS-KB plays a unique part as a coupling component for fast color development, producing vivid oranges, scarlets, and reds in the final shades. Its reactivity provides process flexibility: it couples efficiently with a variety of diazonium salts, keeping acceptance wide across both mass-market and niche pigment systems.

    Formulators in the fiber and textile industries depend on AS-KB for manufacturing pigments with high wash and light fastness, especially when deep, strong reds matter for consumer-facing brands. The product’s behavior in closed system mixers, its dispersability in alkaline liquor, and its resistance to aggregation even when blended with inorganic fillers help color makers keep lines running and minimize surprises in large batch production.

    Direct Insights from the Production Floor

    We have seen plenty of challenges over the years working with Naphthol AS-KB. At scale, even small errors in filtration or inconsistent crystal formation can impact reactivity later on. Our senior technicians remember years where humidity control failed, causing caking and poor shelf-life until we adapted the process and invested in climate control storage.

    Close monitoring goes into each step, from acidification to the refinement of every intermediate. Every kilogram of finished powder passes through particle size analysis—because fines that are too small can clump or create dust during shipping and handling. The team keeps a close eye on off-odor, using sensory testing alongside laboratory data, because a slight amine taint can foreshadow unwanted side reactions or compromise end-use flavor standards in food packaging inks.

    Comparing Naphthol AS-KB to Other Naphthols

    Naphthol chemistry spans a range of similar structures: AS-D, AS-LC, AS-IRG, and others all hold their place, but subtle structural differences influence affinity for certain color shades and processing profiles. For instance, Naphthol AS-D yields more orange and reddish tones when coupled, while AS-LC derivatives typically produce yellows or browns.

    Our experience shows that AS-KB stands out for its compatibility across a broader pH range, letting users adjust their process to suit specific fiber types without overhauling their whole dye kitchen setup. Dyehouses value this latitude, knowing that shifts in liquor composition or small errors in dosing won’t drastically alter the depth or uniformity of shade. Its process flexibility means AS-KB works in both continuous and batch dyeing environments. We have supplied the same product line to facilities making automotive plastic pigments and to partners producing inks for consumer textiles, observing that they achieve consistently stable dispersions without the need for excessive surfactants.

    Applications: Real-World Stories from Long-Term Supply

    One of our longest-running clients produces pigments for high-end outdoor apparel. They insist on using Naphthol AS-KB as the preferred coupling component for their water-fast and light-stable orange shades, pointing out that substituting other naphthols led to fading and patchy effects after repeated sun exposure.

    Another partner in the printing ink field made the switch to our material after fighting issues with inconsistent gloss when printing on coated paper. Our tighter controls over residual metals and inorganic sulfate contaminants meant their final pigments came out clearer, without grit or specks, saving them costly rework and customer complaints.

    We also work with manufacturers of pigment dispersions for engineering plastics, where temperature stability means everything. The AS-KB chemistry endures compounding at elevated temperatures without decomposing or discoloring, which is a challenge for many other intermediates that break down or turn muddy during high-heat processing. Our monthly meetings with their technical staff often focus on tweaking dispersant ratios or adjusting feed rates, but the core intermediate remains Naphthol AS-KB because of its proven performance through years of demanding production.

    Our Continuous Approach to Quality and Traceability

    Production in our facility relies on a combination of automated reactors, manual batch records, and independent lot testing. Each output gets tracked from raw material infeed through to finished drums, with a unique batch history that helps customers trace the origin of every shipment. We share full analytical data on request, including chromatography and spectrophotometry runs, giving partners confidence in reproducibility across orders.

    Beyond instrument readings, our lab and plant teams communicate directly. Weekly meetings review both successes and problems: slight increases in ash after a change in catalyst, detection of off-tints in plate tests, or variable moisture due to shifts in atmospheric humidity. Our in-house lab frequently carries out comparative coupling trials using new and old lots, mimicking customer process conditions by varying solvents, mixing times, and agitation methods so discrepancies turn up before product ever leaves our gates.

    We receive regular feedback from international customers about legislative changes and evolving compliance requirements. Years ago, our staff noticed red flags with some suppliers of starting aromatic amines, which prompted us to shift sourcing and improve documentation long before regulatory pressure escalated. The result has been fewer reject lots, less downtime, and faster response to customer audits.

    Looking Beyond Production — Supporting Partners in Development

    Working as a direct manufacturer means we hear firsthand the headaches that pigment and dye producers face—seasonal demand spikes, changing compliance rules, and rising performance expectations from brand owners. We have invested in well-qualified staff and modern test equipment not just to control manufacturing but to help users experiment with formulas or solve process problems.

    Our technical group offers support for scaling up pilot trials or troubleshooting unexpected shifts in shade or fastness. We’ve assisted partners working with fiber-blended textiles that combine natural cotton with engineered polyesters, adjusting the coupling parameters for AS-KB to achieve optimal pickup and fixation. Those collaborations have helped our clients launch product lines with improved performance, instead of struggling with unpredictable color shifts or patchiness.

    Many times, a pigment or dye formulator will approach us during early-stage product development to discuss compatibility with new additives, resins, or dispersing agents. Our on-site chemists analyze interactions and provide practical solutions, whether it’s recommending pH buffers to prevent hydrolysis during long storage or advising on mixing protocols that keep dispersions stable for months on warehouse shelves.

    Unique Features That Shape Performance

    Our process controls ensure reproducibility from one drum to the next, but performance in real-world conditions depends on more than what analysis can capture. Particle size distribution, water wetting ability, and dusting tendency all factor into how well AS-KB handles in an industrial setting. We know from user feedback that our product’s fine particle distribution avoids both caking and excess dust, which is safer for operators and easier to dose by weight. Well-aged engineers tell us they see less material loss during pneumatic conveying compared to more brittle naphthol grades sourced elsewhere.

    The typical specification for Naphthol AS-KB centers on a finely milled, free-flowing powder with minimal coarse grit. Our drying process stabilizes moisture below 1%, preventing agglomeration, which affects how the powder disperses and reacts. The batch-to-batch repeatability of these physical properties means that end users enjoy reduced waste in their pigment lines, with fewer off-shade lots and less need for emergency troubleshooting.

    We hold AS-KB in high regard for how it maintains shelf stability during months in storage. Its consistent color tone and coupling power hold up without drifting over time, a concern some users expressed after trying similar products from less disciplined sources. This reliability means users can pull inventory from stock without retesting every time, which streamlines their own operations and increases output predictability.

    Challenges, Solutions, and Looking Ahead

    Manufacturing any fine chemical brings its own set of challenges. For AS-KB, maintaining product consistency during scale-up or amid raw material volatility means constant vigilance. Several years back, cheaper intermediates began to appear on the market, tempting buyers with savings. Some of our long-term partners tried these, only to revert to our product after facing complaints from their own downstream customers about unstable shades or unexpected by-products after curing.

    Staying ahead means prioritizing traceable sourcing, in-process analytics, and hands-on involvement of skilled chemists. On occasion, changes in water or solvent purity forced short production halts until new purification steps that fit with current environmental compliance were introduced. We pay close attention to new regulations, always ready to modify processes or retrain our personnel, so that finished Naphthol AS-KB keeps passing ever-tightening international standards for purity and safety.

    We have made incremental improvements over the years: energy recovery systems cut down solvent losses; real-time analytics for residual nitro compounds detect off-spec material before it reaches filling. These investments serve to cut waste, lower environmental impact, and keep consistency at the top of our priorities during every shift.

    The Value of Source-Driven Accountability

    As chemical producers, we are accountable for every drum, every test result, and every impact our manufacturing creates, whether environmental or commercial. Some clients walk our shop floors and review their own shipments at our dispatch docks, knowing that personal connection is often better assurance than a stack of certificates. Skilled technicians who understand both theory and practice take pride in their work, knowing that a trusted product like AS-KB gets built up not by machines alone, but by the efforts and oversight of people who care about the end result.

    Over time, our plant has embraced digital tracking, batch analytics, and direct customer reporting. These tools alone do not guarantee quality, but they keep everyone—from raw material handlers to laboratory analysts—focused on consistency, safety, and performance in the field. Feedback from formulators, pigment designers, and end-users continues to guide even small changes in the way we approach every single batch of Naphthol AS-KB.

    Final Reflections from a Source Committed to Excellence

    Making Naphthol AS-KB in large quantities to a tight specification is a craft, shaped by years of accumulated experience and a willingness to adjust as requirements shift. We are not content to produce the bare minimum; instead, we keep lines of communication open with our partners, see first-hand how the product performs, and never stop asking how we can improve.

    Our reputation among pigment manufacturers, dyers, and plastics colorants suppliers has grown from long-term partnership, listening, and taking pride in doing things right day after day. Naphthol AS-KB continues to stand as one of the most dependable components in color chemistry because we commit to its careful manufacture all the way from the raw intermediate to the finished packaged powder.

    We invite our partners to continue the conversation with us, sharing their experiences and challenges. Working directly with manufacturers means every concern and success feeds back into production, creating better results for both sides. In today’s climate, where end users expect both quality and accountability, these advantages matter far more than surface-level cost savings or empty marketing claims.