Naphthol AS-BS

    • Product Name: Naphthol AS-BS
    • Chemical Name (IUPAC): 3-hydroxy-N-phenylnaphthalene-2-carboxamide
    • CAS No.: 135-65-9
    • Chemical Formula: C16H13NO4S
    • Form/Physical State: Powder/Solid
    • Factroy Site: No.968 Jiangshan Rd., Nantong ETDZ, Jiangsu, China
    • Price Inquiry: sales7@boxa-chem.com
    • Manufacturer: Nantong Acetic Acid Chemical Co., Ltd.
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    Specifications

    HS Code

    840211

    Name Naphthol AS-BS
    Chemical Formula C16H13NO4S
    Cas Number 117-52-2
    Molecular Weight 315.34 g/mol
    Appearance Yellowish powder
    Melting Point 203-205°C
    Solubility Slightly soluble in water, soluble in alcohol and alkali
    Boiling Point Decomposes before boiling
    Usage Azo dye intermediate
    Synonyms 3-Hydroxy-2-naphthanilide-4'-sulfonic acid
    Storage Temperature Room temperature
    Ec Number 204-211-0

    As an accredited Naphthol AS-BS factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Naphthol AS-BS is packaged in a sealed 100g amber glass bottle with a secure screw cap and clear chemical labeling.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for Naphthol AS-BS: 10 metric tons packed in 25 kg bags, loaded onto wooden pallets.
    Shipping Naphthol AS-BS should be shipped in tightly sealed containers, away from heat, sparks, and open flame. Store and transport in a cool, dry, well-ventilated area, following local, national, and international regulations for hazardous chemicals. Ensure containers are clearly labeled and protected from physical damage during transit.
    Storage Naphthol AS-BS should be stored in a cool, dry, and well-ventilated area, away from direct sunlight, heat sources, and incompatible materials such as strong oxidizers. Keep the container tightly closed when not in use to avoid moisture absorption and contamination. Suitable containers include those made of glass, polypropylene, or other inert materials. Store at ambient temperature and label clearly for safety.
    Shelf Life Naphthol AS-BS typically has a shelf life of 5 years when stored in tightly sealed containers under cool, dry conditions.
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    Certification & Compliance
    More Introduction

    Naphthol AS-BS: A Closer Look Through the Eyes of a Manufacturer

    Crafting Quality Naphthol AS-BS: Our Hands-On Approach

    Naphthol AS-BS occupies a firm position in the field of pigment intermediates. Over years of steady production, we've seen what sets this compound apart and why it garners loyalty from dye manufacturers and pigment producers across textile, leather, and plastics industries. Experience passes from one batch to another, right on the shop floor, not through catalogues or empty brochures. Since our earliest days, the aim has been the same: deliver a consistently pure, high-standard Naphthol AS-BS while refusing to cut corners or treat quality as merely a buzzword.

    Producing Naphthol AS-BS means dealing with the subtle differences in raw materials, managing moisture content, keeping crystal purity high, and making sure the pH profile doesn’t drift. Older hands at the plant know where issues may crop up, whether during the diazotization process or after final drying when grain size can influence solubility and dispersibility. The lot-to-lot consistency depends on focus during each stage, with careful eyes watching for the faint red hue and flow characteristics unique to Naphthol AS-BS.

    Key Properties from the Manufacturing Floor

    Chemically, Naphthol AS-BS belongs to the β-naphthol family, derived from β-naphthol and sulfonated aniline intermediates. It carries the formal designation of 3-Hydroxy-2-naphthoic acid, 3-carboxy-4-sulfoanilide. The “BS” suffix signifies a sulfonic acid component that slightly shifts its behavior compared to other siblings in the Naphthol AS series. Over time, these minor molecular tweaks reveal themselves through performance differences in pigment formation, sedimentation rates, and compatibility with diverse substrates.

    Our standard practice ensures that Naphthol AS-BS appears as a faint cherry-red powder. The shade is a visible checkpoint for both the new and seasoned staff, directly reflecting the purity of the intermediates and the care during processing. Water content remains tightly controlled, as either overdrying or incomplete removal can impair its use in pigment coupling. Each kilogram emerges from the plant only after meeting internal benchmarks for residue on ignition, solubility in alkaline solutions, and iron content—details that impact the end user's application results, not just our own sense of accomplishment.

    Real-World Uses: From Factory Floor to Finished Goods

    Naphthol AS-BS stands as a staple for azo pigment production through diazo coupling with a range of diazonium salts, most notably Fast Red RC and Fast Red B. Textile dye houses benefit from its strong affinity with cellulose fibers, often using it to achieve shades of bright reds, oranges, and pinks in cotton fabrics. Tanners deploy Naphthol AS-BS for vibrant leather finishes, exploiting its color fastness and resistance to fading in light or water.

    Some years back, we worked with a client specializing in outdoor upholstery. Their challenge came down to lightfastness and wash resistance. They moved through a whole sequence of naphthol intermediates before settling on AS-BS, due to its ability to provide a clean, bright red without bleeding during washing or exposure to sunlight. Other compounds delivered acceptable results but didn’t match the level of color stability this one offered, especially after repeat testing on finished goods.

    In plastics, the role shifts: here, Naphthol AS-BS proves its value in generating stable, high-tint-value pigments for use in PVC, polyolefin, and polystyrene applications. Customers report that with proper dispersion, color consistency holds up batch after batch, avoiding unexpected hue shifts or migration over time. Advances in plastic additives and compounding technology have only made this more essential, with Naphthol AS-BS remaining at the table as new blends and polymer types emerge.

    Why Naphthol AS-BS Stands Apart

    As a manufacturer, we see Naphthol AS-BS get weighed day in and day out beside other AS-series naphthols. In practice, the “BS” grade provides both an edge and a challenge. Its carboxy sulfo group means better water solubility and often speedier dispersion without clumping, reducing downtime during mixing. Pigment producers who demand ease of dispersion find this especially useful. In direct comparison to Naphthol AS, Naphthol AS-BI, and Naphthol AS-D, the AS-BS model blends more smoothly into high-viscosity pastes and maintains batch-to-batch shade consistency more reliably.

    Past issues with other intermediates—like the stubborn grittiness when using Naphthol AS-D, or the slower uptake on synthetic fibers with Naphthol AS—don’t show up so clearly here. Practically, AS-BS reduces troubleshooting in production runs. Even for new machinery or alternative fiber compositions, its blending window tolerates broader conditions. Operators don’t lose time fighting grainy residues or unpredictable dye yields. Over the years, this reliability saves both effort and money, for both us and our clients.

    Regulatory Commitment and Responsible Manufacturing

    Throughout decades of manufacturing, we've had to navigate evolving environmental expectations, stricter workplace safety guidance, and constant scrutiny over potential aromatic amine release. At one stage, industry-wide recalls for other pigment intermediates drove home the importance of transparency. Our approach involves regular audits, internal testing for amine byproducts, and an open-door policy with regulatory inspectors.

    Industry partners sometimes push for cost-cutting measures that dilute quality or disregard wastewater handling. We hold firm to protocols that keep our effluent streams free of unacceptable aromatic amines, not because of external warnings but through a recognition of the legacy we build through responsible production. Efforts to align with both local and international regulatory standards at our site mean that clients can trace their supply back to a source that actively avoids ecological shortcuts.

    Our site staff understand the knock-on effects downstream. Sloppy batch management or improper discharge impacts not just reputation but long-term access to markets. As regulations tighten—for instance, under evolving standards such as EU REACH and increasingly robust local chemical regulations—manufacturers need to stay ahead. Experience in maintaining clean plant operations means fewer audit surprises and a predictable relationship with authorities and clients alike.

    Challenges Unique to Naphthol AS-BS Manufacturing

    No new chemistry comes free of hurdles. Naphthol AS-BS’s relative sensitivity to impurities requires vigilance at every stage, from the initial choice of naphthol to the use of stainless steel equipment that resists corrosion and contamination. While some pigment intermediates tolerate a broader range of input grades, AS-BS punishes even small oversights through lower yields or off-spec batch colors.

    Repeated recrystallization cycles often become necessary, with careful handling to avoid the kind of charring or discoloration that spoils entire batches. The effort to produce a physically uniform powder means strict management over temperature profiles during both reaction and drying stages. In dry winter climates, sudden shifts in ambient humidity influence moisture content—less experienced producers can end up with caked products that clog feeders at end-user sites.

    Another ongoing adversary comes from iron contamination. Even minute concentrations above allowable thresholds can impact pigment color or catalyze side reactions. Our team responds with regular checks—not just end-product testing, but upstream at the raw material stockpiles and in process tanks. Controlling ferric content isn’t glamorous work, but it marks the difference between a product that behaves as promised and a shipment that prompts field complaints.

    Listening to Industry Trends and Practicing Continuous Improvement

    Designing and producing Naphthol AS-BS at scale means staying alert to what the pigment and dye markets demand. Shifts toward water-based formulations, advances in digital printing, and pressure for greater UV stability all touch the way we approach synthesis and quality control. Our technical team constantly benchmarks products against international competitors, not just ticking off analytical results but performing actual application trials in textile and plastics labs.

    Nearly half of our team has spent over a decade with us, carrying both technical know-how and a sense of pride in problem-solving. Whenever new market requirements come—whether in formulation compatibility, dispersibility, or reduction of specific trace compounds—those voices guide changes to our process flows or purification methods, not consultants or distant regulatory bulletins. Clients have direct access to this internal knowledge base through joint lab trials and post-sales technical support. Stories swap back and forth about process tweaks or oddball requirements, with solutions moving straight from the shop floor to the client’s machinery.

    Supporting Sustainable Chemistry

    Production runs large enough to fill shipping containers inevitably generate waste, from washwater to off-spec residues. Early on, it was common for chemical manufacturers to treat this as an afterthought. Our plant now dedicates a sizeable part of its operation to managing and minimizing this impact—recovering valid intermediates, circulating process water, and reusing cleaning solvents when safe and practical.

    The transition hasn't been simple or accident-free. We learned, for example, that reusing water in the diazotization phase demanded a better filtration step to prevent ghosting in finished batches. Achieving acceptable residue levels required thoughtful scheduling and investment in updated centrifuge systems. Scrutiny from client audits led to further improvements, harmonizing the needs of high purity with real-world environmental pressures.

    Producers in this market face nonstop competition from lower-cost alternatives. We have watched new entrants cut prices, yet run into chronic complaints about unpredictable lot quality or excessive waste. Sustainable methods, while demanding up front, build longer-lived relationships—clients appreciate predictable orders and the transparency that comes when they ask about environmental practices.

    The Future of Naphthol AS-BS and Its Role in Color Chemistry

    Decades ago, options for red azo couplers were limited, and compromises came as part of every batch. Today, relentless demand for higher-quality pigments pushes every manufacturer to innovate or risk getting left behind. Naphthol AS-BS still stands tall thanks to its robust performance across a wide set of applications, from traditional vat dyeing to next-generation synthetic blends.

    Where automation grows, with clients upgrading to closed systems or seeking touchless materials handling for safety and efficiency, our attention shifts to ensuring our product’s free-flowing nature and dust control meet stricter demands. Direct feedback from these clients shapes the physical parameters of our final product. Requests for tighter particle size distribution or improvements in anti-caking properties come straight to production, prompting adjustment rather than resistance.

    Challenges and Solutions: A Day-to-Day Perspective

    Every production run brings its own set of challenges. Even the smoothest process can confront unexpected setbacks: moisture spikes during the rainy season, raw materials showing slightly different purity levels, clients requesting a specific dispersibility profile. The solution rarely lies in abstract process modeling but in knuckling down to test, tweak, observe, and repeat.

    Controlling quality for Naphthol AS-BS starts with training—everyone from the batch operator to the line manager holds responsibility for product outcome, not just the quality control department. The best improvements often begin with observations from the floor: a shift leader noting an off-odor, or a technician spotting trace discoloration during filtration. Rigid adherence to process charts rarely solves these field-level problems. Instead, rapid internal communication and willingness to trial small adjustments ensures problems get solved before they become systemic.

    Clients often come to us with new application ideas or technical hurdles—say, improved wash fastness in poly-cotton blends, or tightening migration limits for toys and children’s goods. Each request becomes an opportunity to re-examine how we produce, purify, and deliver Naphthol AS-BS. Over the years we’ve learned that listening first beats quick standard responses: applications differ, context matters, and our willingness to help test and customize our product builds loyalty.

    Industry Dialogues: What Customers Value Most

    Our years in the market show that pigment and dye producers base purchasing decisions less on theoretical data sheets and more on consistency, support, and the ability to troubleshoot real-world issues. Clients ask about fade resistance on synthetic fibers, water solubility in complex blends, or impurity profiles in medical applications. In answering, our technical teams pull not from marketing brochures but from deep operational experience.

    For example, requests for higher-purity batches for medical use prompted investment in cleaner input streams and improved filtration. Technical support did not just send written guidelines but worked alongside the client through on-site trials. Those collaborations make plain that producing Naphthol AS-BS isn’t an isolated act, but part of a dynamic partnership where change and improvement are the only constants.

    Some long-time clients want their batch-by-batch data sheets in hand before the ships leave port; others require in-person verification at our plant. We accommodate both, drawing from years of shared practice. The most valuable feedback comes not through formal complaints but in the candid conversations that follow a successful product launch, where mutual trust leads to honest appraisals. This exchange informs both current practice and refinements for new markets or end uses.

    Reflections on Reliability and Future Readiness

    Naphthol AS-BS has become more than just a line-item raw material: it acts as a trusted foundation for certain shades of pigment and dye. Our control over purity, moisture, particle size, and chemical profile arises from deliberate, incremental decisions made by people who know that each adjustment can ripple out through a customer’s supply chain. Decades of doing this work builds habits of care—never content to rely on old methods but eager to respond to shifts in customer expectation, regulatory frameworks, and the relentless march of new applications.

    We’ve seen the tragic results that follow short-cutting environmental controls or skimping on R&D: shipments held up at customs, recalls, and worst of all, damaged end-user confidence. By drawing from real manufacturing experience, and balancing attention between plant safety, customer partnership, and regulatory foresight, we believe that Naphthol AS-BS will continue finding its place as more industries look for deeper, more enduring value in their colored materials.

    In recent periods where global supply chains come under pressure, having stable, long-standing relationships with both suppliers and clients means fewer unpleasant surprises. Trust doesn’t ride on the back of price alone; it stems from showing up day after day, learning from mistakes, openly sharing lessons, and treating every shipment as if it defines the next.

    Every Batch Matters: The Manufacturer’s Oath

    To us, Naphthol AS-BS is not just a code or a chemical. Behind the numbers and product grades live the collective experience of an industry that cannot afford half measures. Our track record rests on every kilogram shipped. Whether destined for a textile mill in Asia, a plastics compounder in Europe, or a specialty pigment house in the Americas, each order carries an unwritten promise: made with skill, watched over by knowledgeable hands, and backed by the willingness to listen, improve, and stand behind every result.