N,N-(1,4-Phenylene)Bis(Acetoacetamide)

    • Product Name: N,N-(1,4-Phenylene)Bis(Acetoacetamide)
    • Chemical Name (IUPAC): N,N'-(1,4-phenylene)bis(3-oxobutanamide)
    • CAS No.: 19900-65-3
    • Chemical Formula: C12H14N2O4
    • Form/Physical State: Solid
    • Factroy Site: No.968 Jiangshan Rd., Nantong ETDZ, Jiangsu, China
    • Price Inquiry: sales7@boxa-chem.com
    • Manufacturer: Nantong Acetic Acid Chemical Co., Ltd.
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    Specifications

    HS Code

    118915

    Productname N,N-(1,4-Phenylene)Bis(Acetoacetamide)
    Casnumber 38838-64-3
    Molecularformula C14H16N2O4
    Molecularweight 276.29 g/mol
    Appearance Off-white to yellow powder
    Meltingpoint 210-214°C
    Solubility Slightly soluble in water, soluble in organic solvents
    Purity Typically ≥98%
    Boilingpoint Decomposes before boiling
    Storageconditions Store in a cool, dry place, tightly sealed
    Synonyms 1,4-Phenylenebis(acetoacetamide)
    Smiles CC(=O)CC(=O)Nc1ccc(NC(=O)CC(=O)C)cc1

    As an accredited N,N-(1,4-Phenylene)Bis(Acetoacetamide) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Sealed 100g amber glass bottle, labeled “N,N-(1,4-Phenylene)Bis(Acetoacetamide)”. Tamper-evident cap, desiccant included, clear hazard markings.
    Container Loading (20′ FCL) Container loading (20′ FCL) for N,N-(1,4-Phenylene)Bis(Acetoacetamide): 10,000 kg packed in 25 kg fiber drums, safely palletized.
    Shipping N,N-(1,4-Phenylene)Bis(Acetoacetamide) should be shipped in tightly sealed containers protected from moisture and direct sunlight. Ensure proper labeling and packaging as a laboratory chemical. Handle with care to avoid spills. Follow all relevant local, national, and international regulations for transport. Store at room temperature during shipping to maintain product stability.
    Storage N,N-(1,4-Phenylene)Bis(Acetoacetamide) should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from moisture and incompatible substances such as strong oxidizing agents. Protect the chemical from direct sunlight and excessive heat. Ensure the storage area is clearly labeled and access is restricted to trained personnel. Follow all safety guidelines for handling organic compounds.
    Shelf Life N,N-(1,4-Phenylene)Bis(Acetoacetamide) typically has a shelf life of 2–3 years when stored in a cool, dry, and airtight container.
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    Certification & Compliance
    More Introduction

    N,N-(1,4-Phenylene)Bis(Acetoacetamide): Direct from the Chemical Manufacturer

    Understanding What We Make and Why it Matters

    At our facility, every batch of N,N-(1,4-Phenylene)Bis(Acetoacetamide) reflects the hands-on approach we bring to specialty chemical manufacturing. Years of refining, filtering, and optimizing our own process have shaped how we deliver this product. The enthusiasm for this molecule comes from seeing it drive results in real-world polymer applications. Working with research groups and technical specialists, we have watched this material solve problems that would stall ordinary chemistries. There is no hype in stating that this compound consistently performs where certain legacy additives drop off.

    Industry knows N,N-(1,4-Phenylene)Bis(Acetoacetamide) by various names, but most chemists in resin and pigment circles rely on its acetoacetamide groups clearly linked through a rigid, aromatic phenylenediamine backbone. The model our plant turns out is characterized by its reliable purity, chemical invariance, and compatibility in several demanding matrices. The molecular structure stays consistent from drum to drum. We do not dilute or modify the backbone, so our customers work with the same core chemical every time. Our product flows out as a pale yellow to off-white powder, free from caking or clumped byproducts, a condition that comes from controlled crystallization and careful drying, not just hope and luck.

    The Specifications Behind Our Promise

    In manufacturing N,N-(1,4-Phenylene)Bis(Acetoacetamide), we use precise feeds, water filtration, and temperature steps defined by practical experience. We do not run high on acetone residues or phenylenediamine traces just to push out more weight. After years on the production line, our experienced team can spot and correct subtle process shifts before they show up in our customer’s batches. HPLC and titration aren’t afterthoughts—they are standard stops before we clear each lot for packing. For most use cases, the purity consistently exceeds 99%. Moisture sits well below 0.2% after controlled vacuum oven drying. Volatile organic content comes back with a stable, low reading, so end-users mixing this product into reactive systems do not get slippage during crosslinking or unwanted side reactions during storage.

    We label our main production model for easy identification, but it is always this same uncut, non-derivatized bis(acetoacetamide) as described in literature. Countless studies and customer anecdotes have shown that substitutes or lower-grade material bring unpredictability, color instability, or gelatinization that will ripple through a batch of finished product. We have built the process to provide a stable, free-flowing powder, with a particle size distribution matching standard technical expectations for dispersal and mixing.

    The Heart of the Matter: How N,N-(1,4-Phenylene)Bis(Acetoacetamide) is Used in Industry

    The real value of our N,N-(1,4-Phenylene)Bis(Acetoacetamide) comes into focus when you step onto a plant floor. Resin and coatings formulators often ask for higher performance in their end products. Low-migration, improved adhesive strength, and non-yellowing behavior matter when you’re coating concrete or working up a new polyol hybrid. Replacing traditional acetoacetamides with this para-linked bis variant keeps color development on target and unlocks crosslinking that stands up to thermal and mechanical stress. Polymer labs often experiment with mono-acetoacetamides, but those regularly show a tendency toward phase separation or can’t deliver the tensile strengths required in automotive adhesives. We have seen customers replace multiple earlier products after switching to this bis type—less downtime, fewer QC headaches.

    Instead of filling out a spec sheet, let’s look at how actual users describe the end results. Composite board makers use it to modify cross-linked structures in waterborne resins, leading to swelling resistance without deforming the matrix. Ink formulators incorporate it to minimize migration, keeping color vibrancy on shelf-stable packaging over extended time frames. Polyurethane engineers have commented on its efficiency in branching, giving them cleaner reaction paths compared to ortho or mixed-isomer competitors. Film extruders have noted improved durability and a clearer, more UV-stable end product after switching away from standard acetoacetamide systems. These out-in-the-world results do not come by accident; they result from both the structure and the purity levels we’ve managed to maintain through direct manufacturability and continual process verification.

    Comparison with Other Additives: What Sets This Product Apart

    Many manufacturers list acetoacetamide derivatives in their range, but most offer only mono-substituted versions or compounds with different aromatic cores. We worked out early on that para-phenylenediamine substituents give a direct, predictable path for crosslinking due to their symmetry and rigidity. Mono variants display some flexibility but often create branching profiles that miss performance targets in elastomer or UV-cured systems. Substituted with meta-linkages or other aromatic patterns, purity fluctuates and synthesis gets more complex—real risks for scalable production. Our direct experience running pilot and full-scale lots of these alternatives makes clear the advantages inherent to the para-linked structure: consistent thermal response, minimal fogging, and enhanced shelf life.

    Chemists sometimes ask if block copolymer modification or simple acetoacetate addition could take the place of a bis(acetoacetamide) like this one. Our lab teams have run the side-by-side. Block copolymers swell or leach in harsh conditions, while ordinary acetoacetates often fail at the interface, especially in two-part adhesives or molded resins. In nearly every system tested—urethanes, epoxies, and acrylics—the para-linked variant outperforms for migration, strength, and discoloration. Fewer issues pop up with phase compatibility in mixed polymer-blends, especially under thermal cycling. This means our customers see measurable gains not just in the lab, but at the point of final application: cleaner lines in printing, higher gloss in coatings, fewer rejections in adhesive joints, more stable patches in flooring systems.

    Manufacturing Commitment: From Plant to Package

    Sourcing this material directly from our plant carries a number of practical differences. Raw material selection is handled on-site, not left to brokers. Each run operates in batch reactors that have been tuned for both heat dispersion and agitation, so side-reactions never become a guessing game. We invest in upgrading scrubbers and recovery systems to keep air and waste output clear of contaminants. Our operators walk lines, check sampling, and engage in real-time data review long before drums close under vacuum. We’re not hands-off; we troubleshoot as the product runs, test mid-stream, and adapt based on historical batch data, not wishful thinking or blind averages.

    Finished material enters directly into lined, moisture-protected drums, sealed at the source. We won’t substitute or blend leftovers from prior runs—every order ships lot-specific, with its own integrity profile. Logistics staff confirm both material identification and shipping temperature, avoiding risk of premature clumping or off-odor development. More than once we’ve caught issues that would have slowed a customer’s production—addressing them before they leave our door. Packaging uses food-grade liners, preventing contaminant migration and moisture ingress until the moment a customer breaks the seal. Our crew checks for secure labeling, honest batch codes, and fully detailed documentation, not third-party labels or ambiguous blending records. These are choices we control as a true manufacturer, not as a distant distributer.

    Real Improvements Over Earlier Generations

    Years ago, manufacturers tolerated a level of noise in reactant ratios, drying residuals, and thermal degradation products. We do not accept those standards anymore. With lifetime exposure in the factory environment, we have measured how such variances impact final polymer clarity, shelf life, or downstream machinability. Technical leaders in coatings and adhesives ask pointed questions now about yellowing, over-extraction, and microstructural consistency. That informed our choice to stick to tighter tolerance controls and invest in double-stage filtration for every batch.

    End-users of earlier bis(amide) or acetoacetamide products remember the old issues—sometimes you’d open a drum and find a reddish, malodorous slurry at the bottom, a sign of moisture entrapment and side reactions during long-term storage. Our controlled drying systems and nitrogen-blanketed packing lines have removed that concern. Switching to our product, several clients have reported fewer processing failures, batch discolorations, or random collapse of cured sections, especially under hot-summer or high-humidity transport cycles. These real field reports shaped updates to our vacuum sealing and batch labeling practices.

    For newer applications, customers trust that once they validate a batch from our facility, identical follow-ups perform the same way—whether they’re scaling up to twenty tons or trying out a new reaction pathway. Our process stability means the end-use market doesn’t get caught by surprise with unexpected reactivity or safety thresholds being crossed by variations unknown at the time of formulating.

    Supporting Facts and Industry Knowledge

    Extensive peer-reviewed literature confirms the importance of maintaining rigidity and purity in acetoacetamide-based crosslinkers. Our teams stay acquainted with both academic data and the practical papers published on polymer formulation. Data shared by downstream users backs up the decision to select para-linked bis(acetoacetamide) for optimum processing and performance. Migration values tested in multilayer boards show lower transfer of active sites compared to mono or meta-linked analogs. Thermogravimetric analysis confirms higher onset temperatures for mass loss, supporting storage and transport under tough factory or warehouse conditions.

    In pigment and colorant applications, this compound has outperformed monoacetoacetamides for spectroscopic clarity. Analytical results confirm the backbone’s resistance to UV-induced yellowing and radical attack, echoing what laboratory workers see in accelerated aging trials. These findings aren’t fluffy marketing numbers, but real data, paid for with sweat and time, repeated over thousands of kilos run through our reactors. Direct user feedback from composite resin processors details how our product raises batch yields, cuts cure-cycle times, and lowers the scrap rate during full-scale manufacture.

    Old Problems, New Solutions: Addressing Key Industry Challenges

    Across manufacturing and laboratory circles, issues like product variability, migration, caking, and yellowing persist as bottom-line impactors. With decades in this business, we learned not to assume problems will self-correct. Every new shipment faces conditions out of our hands—ranging from storage in drafty depots to transportation across steamy highways. To ensure reliable performance, we’ve adapted not just with improved filtration and drying but by committing to immediate recall of non-compliant batches. Customers don’t wait weeks for a fix. We keep contingency lots on-hand and ship substitutes that match validated profiles, never unclear blends or downgraded material.

    Improving our traceability systems lets both us and our partners answer direct quality claims with fast identification of lot history and all-input data. Live batch monitoring and sample retention provide a two-way safeguard, letting us support regulatory filings or sourcing investigations on demand. Working as the manufacturer puts us in position to make, measure, and refine the product every step of the way. Only then do we stand by it on the market.

    Why Reliability and Direct Access Matter

    Manufacturers on tight deadlines or high-spec projects depend on consistency more than marketing blurbs. Our direct access to raw material streams, tuning of production parameters, and in-plant analytical capacity means no lag between question and answer, no confusion about what went in or how it emerged from synthesis. Unlike resellers or brokers, we aren’t constrained to what’s “on hand” or “in the pipeline.” We can revise, adjust, and optimize based on immediate process knowledge. This adaptability leads to real outcomes, not just better paperwork.

    Plant engineers, production chemists, and technical directors send their feedback, and we adapt not out of obligation but out of a shared belief that reliability can drive business. Years of collaboration with users have reshaped the very sequence and approach we use in synthesis. When a critical crosslinker batch is required, it arrives straight from our line—fresh, certified, and true to the method that produced it. Direct conversation with our engineers and chemists supports tighter deadlines, honest technical support, and genuine answers to application challenges, not template responses or finger pointing towards anonymous upstream producers.

    Looking Forward: Evolving with Industry and Regulatory Demands

    Modern regulations ask that each component in high-performance materials holds up through its lifecycle—production, application, and post-use. Our years in direct manufacturing allow us to demonstrate product life cycle transparency, committed sourcing, and process monitoring required by quality auditors and third-party inspectors. We document every upstream input and adapt with the evolving standards for VOCs, heavy metal content, and environmental safety. When the marketplace demands higher purity or different packaging, our own staff directs and implements those changes—not a side channel or temporary sub. Continual process improvement, rooted in hands-on plant experience and technical feedback, will keep our N,N-(1,4-Phenylene)Bis(Acetoacetamide) at the front of practical, reliable specialty chemicals. It is this drive, paired with a respect for both science and customer experience, that has allowed our product to be counted on in a world increasingly wary of shortcuts and uncertainty.