Di-alpha-naphthol

    • Product Name: Di-alpha-naphthol
    • Chemical Name (IUPAC): 2,2'-Binaphthalen-1-ol
    • CAS No.: 135-19-3
    • Chemical Formula: C20H14O2
    • Form/Physical State: Solid
    • Factroy Site: No.968 Jiangshan Rd., Nantong ETDZ, Jiangsu, China
    • Price Inquiry: sales7@boxa-chem.com
    • Manufacturer: Nantong Acetic Acid Chemical Co., Ltd.
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    Specifications

    HS Code

    383751

    Chemical Name Di-alpha-naphthol
    Cas Number 135-19-3
    Molecular Formula C20H14O2
    Molecular Weight 286.33 g/mol
    Appearance Off-white to pale yellow solid
    Melting Point 220-222°C
    Solubility In Water Insoluble
    Solubility In Organic Solvents Soluble in alcohol, ether, and benzene
    Density 1.315 g/cm3
    Synonyms 1,1'-Bi-2-naphthol; BINOL; 1,1'-Bi-2-naphthol
    Smiles C1=CC=C2C(=C1)C=CC=C2C3=CC=C4C(=C3)C=CC=C4O
    Ec Number 205-180-1
    Pubchem Cid 68993
    Hazard Statements May cause eye, skin, and respiratory irritation

    As an accredited Di-alpha-naphthol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Di-alpha-naphthol is packaged in a 500g amber glass bottle with a secure cap, labeled with hazard warnings and chemical information.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for Di-alpha-naphthol: Typically loaded with 12-14 MT in 25kg bags/drums, maximizing safe storage and shipment.
    Shipping Di-alpha-naphthol should be shipped in tightly sealed containers, protected from light, moisture, and incompatible materials. It must be clearly labeled and packaged according to local and international regulations. Transport at ambient temperature with proper documentation, and ensure handling by trained personnel, following relevant safety and hazard guidelines.
    Storage Di-alpha-naphthol should be stored in a tightly sealed container, away from light, moisture, and incompatible substances such as strong oxidizers. Store in a cool, dry, and well-ventilated area, ideally in a designated flammable materials cabinet. Proper labeling and secure storage are essential to prevent accidental exposure or contamination. Avoid heat sources and ensure storage area is free from ignition sources.
    Shelf Life Di-alpha-naphthol typically has a shelf life of 2–3 years when stored in tightly sealed containers in a cool, dry place.
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    Certification & Compliance
    More Introduction

    Introducing Di-alpha-naphthol: Our Experience Manufacturing a Key Chemical Intermediate

    What Sets Di-alpha-naphthol Apart

    Producing Di-alpha-naphthol is a labor-intensive and knowledge-driven process. In our line of work, few intermediates bridge the gap between foundational raw chemicals and advanced end products like di-alpha-naphthol. With decades spent refining our approach to the synthesis and purification of aromatic compounds, we've found that the molecular stability and consistent reactivity of our di-alpha-naphthol (model: DAN-1) make it indispensable for downstream manufacturing.

    The close arrangement of the two naphtholic groups forms a solid backbone for coupling reactions, providing a reliable basis for pigment industries. In our factory, every batch is tailored from the same quality-assured naphthalene sources, and we use proven procedures to maintain a consistently high content, typically upwards of 99%. Our chemists keep a close eye on particle size, moisture content, and trace impurity levels since even minor contaminants complicate further synthesis down the production line.

    After countless runs through our reactors and filtration setups, we can say that di-alpha-naphthol stands out from other naphthol isomers not just in structure, but in how it responds under process conditions. Its reactivity profile suits azo coupling far better than many analogues you might find, such as beta-naphthol or mono-naphthol. The reactivity this molecule brings simplifies many common dye and pigment applications, letting manufacturers achieve deeper shades or more resistant bonds with fewer additives and less reprocessing.

    Meeting Evolving Industry Needs

    Down on the shop floor, pigment producers, laboratories, and pharmaceutical plants often speak about reliability and purity. Subtle differences in synthesis can mean the world for these users. Through hundreds of feedback cycles, we refined the washing, drying, and stabilization phases. This isn’t just so we can tick boxes; we know a patchy di-alpha-naphthol lot creates troublesome precipitates and inconsistent color yield. By keeping melting point, HPLC profiles, and contamination under tight control, we reduce surprises for our customers and help them maintain product standards.

    We’ve also seen a marked shift toward stricter safety and environmental standards in recent years. That means regular solvent testing, better effluent treatment, and more rigorous internal audits. Waste handling for di-alpha-naphthol presents a bigger challenge compared to simpler naphthols due to its dimeric structure—certain by-products are less common and need specialized disposal. We responded by fine-tuning our synthesis route and containment strategies. Our transition to greener oxidizing agents brought down emissions, while robust containment keeps losses minimal, even in continuous processing.

    Our regular users say that with our di-alpha-naphthol, they experience fewer choked reactors and lower filter cake loss. That’s usually the sum of countless minor improvements along our process timeline—optimized reagent ratios, upgraded centrifuges, more careful storage before shipping. Our technical team routinely shares best practices, ensuring downstream users avoid solvent incompatibilities or polymerization issues that sometimes crop up with lower-quality di-alpha-naphthol.

    Applications: Why Di-alpha-naphthol Remains a Cornerstone

    Most of the di-alpha-naphthol that leaves our plant heads into pigment and dye synthesis. For anyone making azo dyes, it provides a steady, reliable foundation. The way the two naphthol units are joined allows for strong conjugation, deepening the color base and strengthening sunlight resistance. Customers producing high-grade red or maroon pigments often report sharper hues and longer color retention when they use our material.

    Some years back, we started getting requests from the pharmaceutical sector. After several rounds of validation, leading labs began using our di-alpha-naphthol as an intermediate for specialty drugs. The reasoning is straightforward: its unique configuration speeds up synthetic transformation, helping keep pharmaceutical yields up and side-products down. While pigments remain our largest segment, specialty chemical companies and API manufacturers return for our product due to its reproducibility and particularly clean conversion rates.

    On top of this, research centers and universities seek out our di-alpha-naphthol for bench-scale and pilot experiments. Feedback from these groups often shapes our protocols; university labs, in particular, give us clear and detailed results concerning crystallinity and solubility in a variety of solvents. By learning from these small-scale projects, we sometimes discover small kinks in our purification sequence. It’s not an exaggeration to say that the input from academic partners helps us maintain a level of quality control that isn't easy to find elsewhere, especially as more research pivots toward novel pigment structures or pharmaceutical scaffolds.

    Practical Knowledge: Handling, Safety, and Consistency

    Years handling di-alpha-naphthol have taught us a few lessons. The solid form we provide has a light yellow-brown color and a distinctive smell—characteristic cues we check for at every stage. We package and transport our product in sealed, inert-lined drums to prevent oxidative changes. Moisture is the mortal enemy here, as even trace amounts can lead to slow degradation and the formation of tars that reduce reactivity.

    Plant technicians across different user companies report that our batches have excellent shelf-life and low tendency to clump, even after several months in standard warehouse conditions. That comes down to deliberate choices in post-crystallization drying and rapid transfer to packaging. We run regular stability studies ourselves. Formaldehyde and similar decomposition products remain under strict regulatory limits throughout our supply chain.

    Safety always sits high in our minds. Di-alpha-naphthol, like its relatives, has specific occupational limits to observe, and dust can create local irritation for workers performing large-scale processing. So we keep particle size above ultra-fine levels to minimize airborne dispersion, supporting good facility ventilation and healthy air quality. Common personal protective equipment handles the potential risks, and we share tailored handling guidelines directly with our customers, based on the size and conditions of their facilities.

    Product Differences: How Di-alpha-naphthol Stands Out from Other Naphthols

    A lot of customers ask why we continue putting so much effort into di-alpha-naphthol, when beta-naphthol or mono-alpha-naphthol already exist and are found in the market. The short answer: the chemistry is just different. Each has its own strengths, but the dimeric structure of di-alpha-naphthol unlocks additional reactivity and stability that single-ring analogues just don’t possess.

    For pigment production, using beta-naphthol often limits the achievable spectrum and weather resistance. With mono-naphthol, the complications usually set in during large-volume synthesis: higher impurity formation and less predictable reactivity, not to mention a narrower workable pH window. Di-alpha-naphthol handles the tough stuff. Coupling reactions proceed more smoothly, with fewer by-products that gum up equipment or force rework of entire batches.

    On an industrial scale, downtime costs time and money. We keep hearing from regular partners how shifting from single-naphthol based formulas to our di-alpha-naphthol reduces both batch failures and purification steps. This is no accident—it ties back to the molecular overkill that comes from the dimeric linkage, which stays stable under tough process conditions and resists unwanted oxidation far better than the alternatives.

    In pharmaceutical manufacturing, accuracy counts. Here, our product maintains fine-tuned melting ranges and consistent analytic profiles, which reduces reruns and purification headaches. Formulators regularly find fewer side reactions, a smoother work-up, and a higher selectivity for their active intermediates. Those working with mono- or beta- series naphthols often wrestle with poor crystallinity and harder-to-remove residuals, eating up time in the purification stages. Di-alpha-naphthol simply isn’t as fussy, letting chemists focus on process development and product innovation instead of damage control.

    How Our Production Approach Reflects Industry Change

    We run a tightly integrated workflow, from sourcing naphthalene feedstock to final product shipping. Over the years, regulatory changes and customer demands have evolved, but the fundamentals of clean, consistent output remain unshakable. These days, customers expect clear Certificates of Analysis for every lot and often request data on trace solvents, heavy metals, or non-volatile residues. We deliver this as standard, routinely exceeding published thresholds and responding quickly to requests for data packs or specialized analysis.

    Years back, bulk pigment users just wanted stable color and good dispersibility. Now, the questions dig deeper: “How sustainable is your process?”, “Can you provide impurity profiles for global registration?”, “What’s your energy consumption per ton of output?” We track, compile, and reduce this data in a way that's become second nature in our daily operations. While we used to focus almost exclusively on end-product quality, we’ve come to realize how much customers rely on process transparency—especially when exporting to jurisdictions with varying compliance requirements.

    We collaborate with industry groups and local regulators, attending annual chemical safety trainings, submitting emissions data, and participating in national clean technology projects. We reinvest these learnings into our core production systems, whether by trialing new catalysts or experimenting with solvent recovery. This mindset doesn’t just help satisfy customer audits; it actually improves material consistency and minimizes cost overruns and unexpected plant shutdowns.

    We believe every successful batch teaches us something useful. Decades of troubleshooting, batch failure analysis, and listening to user pain points have codified a production system that actively learns. We keep our doors open to feedback, whether that’s a pigment formulator needing a tighter particle size spread or a pharmaceutical company requesting a new impurity spec. As these requests come back in cycles, our technical and production teams exchange real-world findings to collectively elevate quality.

    The Future of Di-alpha-naphthol Manufacturing

    Looking ahead, we see a clear path toward even greater material consistency and environmental responsibility. More pigment users want to shrink their own environmental footprints, so we’re investing in further process control automation and closed-loop filtration. By keeping emission points documented and recovery rates optimized, we can offer cleaner supply chains and tap into emerging global green chemistry initiatives.

    We also watch the regulatory space very closely, especially as national and international authorities introduce new workplace safety guidelines. Adapting quickly is a survival skill in our sector. Worker exposure gets monitored; waste streams get logged and treated; every variable in the process gains a tracking code. These habits have built lasting relationships with customers who know what to expect each time they order from us.

    Technological advances also play a part. Automation helps us eliminate operator error, while digital tracking gives instant access to batch origins, impurity profiles, and manufacturing conditions. We use data from hundreds of real-world applications to guide improvements—advice from a dye house that wants better dispersibility, lab feedback asking for higher clarity in solution, or a multinational partner requesting automatic compliance with shifting regulatory landscapes.

    Building Trust Through Real-World Experience

    Trust comes from consistency, not from marketing claims. Over the years, we’ve seen competitors come and go, many promising lower prices or bigger volumes. The long-term relationships we have built reflect an unwavering focus on product quality, real-world usability, and direct collaboration with the people who rely on di-alpha-naphthol for smooth-running operations.

    We don’t sell promises, we deliver solutions, batch after batch. It means investing in the right talent, the best raw materials, rigorously maintained equipment, and a culture that values open channels between our plant floor and our customers’ production lines. Whenever a new industry standard emerges or a user brings up a recurring issue, we turn our findings into better material. It’s a cycle—continuous improvement tied to the feedback loop between us and our users.

    By sharing clear data and taking direct responsibility for every container of di-alpha-naphthol we ship, we offer a foundation of reliability. Our experience shows in the little things: shipments that arrive on time, documentation that answers questions, product that integrates easily into existing process flows. These are values we cultivate because we have as much at stake in our customers’ success as they do.

    Our Commitment: Raising Standards for Di-alpha-naphthol

    As the landscape of industrial chemistry evolves, we will keep improving our di-alpha-naphthol production to meet and exceed the challenges of tomorrow. Chemical manufacturing is about more than just molecules; it’s about the people, the process, the patience, and the persistence that translate raw inputs into solutions customers actually need. This hands-on, feedback-driven approach remains at the heart of what we do.

    Every container that leaves our plant carries the weight of decades of learning, ten thousand process refinements, and a guarantee built on facing and solving real industrial problems. Our di-alpha-naphthol lets partners streamline their own manufacturing, improve product quality for their customers, and stay ready for new trends in environmental safety and end-use performance.

    The end goal never changes—to supply a chemical intermediate that supports industry progress, minimizes operational headaches, and holds up under tough real-world conditions. Open communication, shared learning, and mutual respect between manufacturer and user define our business. We take pride in every successful batch and stand ready to answer the next technical challenge with the same drive that has powered us through years of growth.