1-naphthol-4-sulfonic acid

    • Product Name: 1-naphthol-4-sulfonic acid
    • Chemical Name (IUPAC): 4-hydroxynaphthalene-1-sulfonic acid
    • CAS No.: 96-99-1
    • Chemical Formula: C10H8O4S
    • Form/Physical State: Solid
    • Factroy Site: No.968 Jiangshan Rd., Nantong ETDZ, Jiangsu, China
    • Price Inquiry: sales7@boxa-chem.com
    • Manufacturer: Nantong Acetic Acid Chemical Co., Ltd.
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    Specifications

    HS Code

    214249

    Chemical Name 1-naphthol-4-sulfonic acid
    Molecular Formula C10H8O4S
    Molecular Weight 224.23 g/mol
    Cas Number 84-87-7
    Appearance White to off-white powder
    Melting Point Around 240°C (decomposes)
    Solubility In Water Soluble
    Pka 1.2 (sulfonic acid group)
    Density 1.59 g/cm³
    Synonyms Schaeffer’s acid; 4-Hydroxynaphthalene-1-sulfonic acid
    Boiling Point Decomposes before boiling
    Storage Conditions Store in a cool, dry place
    Ec Number 201-549-2

    As an accredited 1-naphthol-4-sulfonic acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1-Naphthol-4-sulfonic acid is packaged in a 100g amber glass bottle, tightly sealed and labeled with hazard and handling instructions.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for 1-naphthol-4-sulfonic acid: Typically packed in 25kg bags, totaling about 12–14 metric tons per container.
    Shipping 1-Naphthol-4-sulfonic acid should be shipped in tightly sealed, corrosion-resistant containers, protected from moisture and incompatible substances. The package must be clearly labeled and handled as a chemical substance. Transport should comply with applicable regulations for hazardous materials, ensuring safety from leaks, spills, and physical damage during transit.
    Storage 1-Naphthol-4-sulfonic acid should be stored in a tightly sealed container, away from moisture and incompatible substances such as oxidizers. It should be kept in a cool, dry, well-ventilated area, protected from direct sunlight and sources of ignition. Properly label the storage container, and ensure access is limited to trained personnel following appropriate chemical safety protocols.
    Shelf Life 1-Naphthol-4-sulfonic acid has a shelf life of about 2-3 years when stored tightly sealed, cool, and away from light.
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    Certification & Compliance
    More Introduction

    Introducing Our 1-Naphthol-4-Sulfonic Acid: Direct From the Source

    Built From Chemistry, Not from Brochures

    We have worked with naphthol derivatives on a daily basis for decades, tracking every shift in batch quality, raw material markets, and demands from dye houses and pharmaceutical developers. Our 1-naphthol-4-sulfonic acid, known in the lab as 4-hydroxy-1-naphthalenesulfonic acid or Schaeffer’s acid, comes from a process route we have optimized for both industrial scale and reproducibility.

    In our own facilities, we start with naphthalene, sulfonate at the fourth position, and hydroxylate at the first, using clean intermediates. Each stage gets monitored—by eye, by HPLC, and sometimes just by smell. Because we handle every step, from naphthalene through to the purified sulfonic acid, trace impurities from incomplete sulfonation or off-target isomers never build up and never find their way into the final barrel. You can check the sulfonic acid content, color, and iron residue on every lot. Our technical teams adjust parameters every campaign, watching how even small shifts in temperature or pH can tilt the yield or skew the product color.

    Why This Compound Matters in Practice

    Scholarly journals say 1-naphthol-4-sulfonic acid serves mainly in dyes, pigments, pharmaceuticals, and sometimes as a coupling agent. Researchers love writing about it because it is, in their eyes, a classic intermediate: a molecule with defined reactivity and solid historical use. From where we stand, the job is more practical. Only certain grades actually work when forming azo dyes for textiles. Only the cleanest material will avoid tints in pharmaceutical intermediates, and some grades just will not dissolve right for fine chemistry.

    We spent years breaking down feedback from end-users, many of whom never see our name but do see clogs in their filters or streaks in their finished products. Textile plants, for example, stress every detail of powder flow or wetting properties. Some pigment customers swear our material runs cleaner in continuous reactors. Pharmaceutical teams push us for lower metals, lower colored contaminants, tighter control over free sulfonic acid—down to parts per million. We built our facilities to answer these demands. Instead of one size fits all, we run different purifications, use different drying methods, and swap process water for higher-purity requirements.

    Core Specifications and Real-World Demands

    Several grades pass through our dryers and blenders each month. Most customers want powder at ≥98% purity, water-soluble, and with low heavy metals. Others demand granules rather than powder, to keep dust down in automated handling equipment. Pharmaceutical partners track organic impurities to below 0.1%.

    In practical terms, the grade going to dye intermediates isn’t identical to what a pharma API manufacturer requests. We see the difference under the light: one needs near-colorless crystals, the other is fine with a slight tan. Some complain about the faint odor, but that just confirms decent shelf-life and no in-process oxidation. Granule density matters in big dye tanks, but lab researchers care much more about clarity of solution and filterability. No two orders get handled the same unless the application details match perfectly. That comes from working closely with buyers and bench chemists, not following a script.

    Typical physical attributes you will spot from our material: free-flowing powder (or dust-free granules on request), true melting point in the 229–234°C range, and rapid dissolution in water. Some competitors sell dusty, amber-tinted lumps, not our style—years of feedback tell us why uniformity in this specific intermediate brings fewer headaches downstream. Trace iron, copper, and phosphorus—always well below 10 ppm, and usually lower, depending on the environment where the compound gets used next.

    The Real Differences: Our 1-Naphthol-4-Sulfonic Acid Versus Others

    We pay close attention to what sets our Schaeffer’s acid apart from what is stacked on a dock somewhere else in the world. Methods vary: some competitors use lower-grade naphthalene, cut back on purification steps, or repackage industrial byproducts as fine chemical intermediates. This brings visible and invisible faults, especially if you put material into sensitive synthesis. Our hands-on route ensures higher consistency between batches. Every production run brings subtle changes, but our teams track them by logging production data, not just shipping receipts.

    Much of what we see in the market comes from resellers or brokers, who tag on a general certificate and rarely guarantee critical specs beyond “white powder, water soluble.” That fails actual users when off-odors, color, or metal content disrupt the chemistry. Our own chemists and operations team feel the pressure of each order, and we never see our job as shipping a role number and hoping for the best. Those differences show up in process runs, syntheses that finish faster, and fewer shutdowns to clean equipment.

    For customers who have run into supply problems with spot-market origin material, shifting to our supply brings down unknowns. A decade of experience shows in every sample sent out. We see it in reorders and even in complaints, which always push our process control tighter next time.

    Common Uses: Not Just on Paper, But in Practice

    Textbooks list dye intermediates, pigments, pharma intermediates, and fine chemicals as core uses for 1-naphthol-4-sulfonic acid. Our customers show us what this really means across industries. In azo dye manufacture, for example, this compound links with diazonium salts to build vivid reds and oranges, the kind used for cotton and wool. Quality here depends on the purity and wetting of the acid—off-spec supplies leave behind streaks or washed-out fibers. Some food dye makers, following very strict contamination rules, request extra testing, which our QA team handles individually on each consignment.

    In pharmaceuticals, Schaeffer’s acid creates intermediates for anti-infectives and other APIs. The FDA and equivalent agencies look for trace impurities or heavy metals, and our pharma lines run separate from our dye lines for this reason. Lab techs and production chemists stop by our plant to see real-time QC checks, and we let their audits drive tweaks to purification.

    A few customers still use 1-naphthol-4-sulfonic acid for sensors and specialty resins. These accounts demand extremely low levels of colored contaminants, since anything left behind disturbs spectra or gelation steps. We customize drying and packing to avoid any kind of trace plasticizer, which can leach into high-purity resins. Most brokers or resellers never receive this feedback, but we see it almost every quarter.

    Handling the Chemistry and Real-World Supply

    Sometimes, buyers run into trouble from poor handling, transit, or packaging. Our response was to develop triple-sealed drums, foil liners, and inert gas blanketing for the best grades. Bulk users receive anti-caking powder for bulk loading. Small-volume labs prefer sealed packs. This all comes from years of direct complaints—lumpy, wet, or yellowed product makes its way back to us, and that makes us tighten process and logistics.

    We do not just manufacture and forget. Ongoing market changes require us to keep raw naphthalene sourcing tight and support alternative purification steps when crude supply fluctuates. Energy prices, labor, and even regional water purity matter for batch consistency. Situations where rogue batches slip into dye plants happen globally; we invest in redundant QC, traceability, and a sample retention library just to rule out such stresses from our end. Any recalls or disputes always come straight back to operators and manufacturing engineers, never to a third-party office.

    Our technical support team knows the actual plant, not just standard answers. Experienced directly, each customer problem—whether in India, Europe, or the Americas—gets related back to the actual reactors. Adjustments to synthesis conditions sometimes mean changing how a batch looks or feels, and we cycle these adjustments transparently to each repeat customer. Only by owning core production do we deliver exact requirements, as routine quality checks in the warehouse never fix a poor upstream batch.

    Supporting Quality Beyond the Product

    We do not stop with delivery. Many customers return with analytical data, seeking matching samples or batch-to-batch guarantees. We keep reference samples for years, so, if a question or quality dispute comes up, chemists can investigate side-by-side. Details matter—whether that means bottle types for high purity, or coordinating shipping during temperature swings.

    We audit and verify all supporting chemicals and packaging against latest regulatory standards, and adjust processes ahead of changing global standards. Not every plant does this proactively, but pressure from food, pharma, and specialty dye users means we must. This comes from years in the field, supporting compliance audits where every tiny impurity gets tracked.

    Every claim passes through in-house labs—no theoretical data, just real measurements available for review. Our process staff works closely with both customers and logistics, ensuring that not just chemical quality but all handling elements support robust final results.

    Troubleshooting: Responding to Real-World Issues

    Over the years, we learned that not every problem can be solved on the first round. Temperature spikes during shipping sometimes bring a sticky product, and overdrying can lead to clumping. Instead of leaving customers to solve these alone, we work with plant operators and QA labs to adjust shipping or provide on-site technical support. If a shipment does not meet specs, we track the production record, audit the process log, and release replacement batches promptly.

    Dust remains a complaint from many dye plants; we introduced granulated and coarser grades that flow better and produce less dust when loaded. Not every buyer wants the same solution, which means we regularly tweak granule size, blend in anti-caking agents, or recommend pneumatic transfer instead of manual loading. We expect regulatory changes—such as lower limits on heavy metals or persistent organic pollutants—to tighten further. Our process teams anticipate these rules, adapting materials and reagents so our supplies remain in line with incoming requirements rather than simply catching up.

    We have occasionally found that regional water impurities in customer plants cause product settling or precipitation. Our teams investigate, recommend mixing protocols, or adjust powder grades suited for better dissolution. Working so closely with end users means continuous feedback improves each production cycle, making the next batch smoother to process.

    What Experience Teaches: Ongoing Evolution

    Over several decades, industry demands have shifted. At times, the biggest challenge was supply chain disruptions; at others, it became about passing the latest regulatory limits or meeting different user expectations on purity. Supporting that requires not just chemistry, but deep process understanding and direct relationships with actual customers, not just distributors or brokers.

    Years of trial and error improved both our product and our customer communications. Customer feedback prompted us to tweak everything from the order form to the final QA release process. Some improvements came from engineered solutions—like dedicated process lines for pharma material—while others grew from the ground up through partnership with end-users.

    We see the faces behind every order. Whether it is a textile mill needing hundreds of tons or a specialty lab running a novel polymerization, we look at each order as a partnership. Only those who handle raw chemical production understand the real impact contaminants or off-grade material bring. Every lot carries our commitment—not just molecules in a sack, but the result of decades of learning, monitoring, adjusting, and delivering.

    Conclusion: The Value of Manufacturer-Led Quality

    Every batch, every audit, every technical discussion ties back to the realities of large-scale chemical production. From process innovation to end-user application support, the quality and consistency of our 1-naphthol-4-sulfonic acid grows out of deep craft and constant adaptation. Those working directly in the chemistry, not just selling products, see and solve the hidden challenges before they ever appear in a downstream process or finished product.

    We work on continuous improvement, face every plant audit, and listen closely to all feedback. This direct manufacturing experience, open dialogue with end users, and commitment to real chemistry keep our product a reliable choice for current and next-generation applications.